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Technical Paper

Optimization of Surfactant and Catalyst Modified Urea-Water Solution Formulation for Deposit Reduction in SCR Aftertreatment Systems

2022-03-29
2022-01-0541
Selective Catalytic Reduction is the primary method of NOX emission abatement in lean-burn internal combustion. This process requires the decomposition of a 32.5 wt. % urea-water solution (UWS) to provide ammonia as a reducing agent for NOX, but at temperatures < 250 °C the injection of UWS is limited due to the formation of harmful deposits within an aftertreatment system and decreased ammonia production. Previous work has sufficiently demonstrated that the addition of surfactant and a urea/isocyanic acid (HNCO) decomposition catalyst to UWS can significantly decrease deposit formation within an aftertreatment system. The objective of this work was to further optimize the modified UWS formulation by investigating different types and concentrations of surfactants and titanium-based urea/HNCO catalyst. Because there is a correlation between surface tension and water evaporation, it was theorized that minimizing the surface tension of UWS would result in decreased deposit formation.
Journal Article

Investigation into Low-Temperature Urea-Water Solution Decomposition by Addition of Titanium-Based Isocyanic Acid Hydrolysis Catalyst and Surfactant

2020-04-14
2020-01-1316
Mitigation of urea deposit formation and improved ammonia production at low exhaust temperatures continues to be one of the most significant challenges for current generation selective catalytic reduction (SCR) aftertreatment systems. Various technologies have been devised to alleviate these issues including: use of alternative reductant sources, and thermal treatment of the urea-water solution (UWS) pre-injection. The objective of this work was to expand the knowledge base of a potential third option, which entails chemical modification of UWS by addition of a titanium-based urea/isocyanic acid (HNCO) decomposition catalysts and/or surfactant to the fluid. Physical solid mixtures of urea with varying concentrations of ammonium titanyl oxalate (ATO), oxalic acid, and titanium dioxide (TiO2) were generated, and the differences in NH3 and CO2 produced upon thermal decomposition were quantified.
Technical Paper

System Level Simulation of H2 ICE after Treatment System

2024-04-09
2024-01-2625
Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.
Technical Paper

Performance Evaluation of an Eco-Driving Controller for Fuel Cell Electric Trucks in Real-World Driving Conditions

2024-04-09
2024-01-2183
Range anxiety in current battery electric vehicles is a challenging problem, especially for commercial vehicles with heavy payloads. Therefore, the development of electrified propulsion systems with multiple power sources, such as fuel cells, is an active area of research. Optimal speed planning and energy management, referred to as eco-driving, can substantially reduce the energy consumption of commercial vehicles, regardless of the powertrain architecture. Eco-driving controllers can leverage look-ahead route information such as road grade, speed limits, and signalized intersections to perform velocity profile smoothing, resulting in reduced energy consumption. This study presents a comprehensive analysis of the performance of an eco-driving controller for fuel cell electric trucks in a real-world scenario, considering a route from a distribution center to the associated supermarket.
Technical Paper

A Solution for a Fail-Operational Control of Steer-by-Wire System without Mechanical Backup Connection

2021-04-06
2021-01-0931
The past five years have seen significant research into autonomous vehicles that employ a by-wire steering rack actuator and no steering wheel. There is a clear synergy between these advancements and the parallel development of complete Steer-by-Wire systems for human-operated passenger vehicle applications. Steer-by-Wire architectures presented thus far in the literature require multiple layers of electrical and/or mechanical redundancy to achieve the safety goals. Unfortunately, this level of redundancy makes it difficult to simultaneously achieve three key manufacturer imperatives: safety, reliability, and cost. Hindered by these challenges, as of 2020 only one production car platform employs a Steer-by-Wire system. This paper presents a Steer-by-Wire architectural solution featuring fail-operational steering control architected with the objective of achieving all system safety, reliability, and cost goals.
Technical Paper

A 2-D Computational Model Describing the Flow and Filtration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980545
A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.
Technical Paper

Conjugate Heat Transfer Analysis of an i-4 Engine including Pistons, Liners, Block, Heads, Water Cooling Jacket, and Oil Cooling Jets

2024-04-09
2024-01-2696
Internal combustion engine (IC engine) vehicles are commonly used for transportation due to their versatility. Due to this, efficiency in design process of IC engines is critical for the industry. To assess performance capabilities of an IC engine, thermal predictions are of utmost consequence. This study describes a computational method based on unsteady Reynolds-averaged Navier–Stokes equations that resolves the gas–liquid interface to examine the unsteady single phase/multiphase flow and heat transfer in a 4-cylinder Inline (i-4) engine. The study considers all important parts of the engine i.e., pistons, cylinder liners, head, block etc. The study highlights the ease of capturing complex and intricate flow paths with a robust mesh generation tool in combination with a robust high-fidelity interface capturing VOF (Volume-of-Fluid) scheme to resolve the gas-liquid interfaces.
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